Blisters are such a drag, sorry you are dealing with such things right before your time in the Whites. Sometimes it is not worth the struggle and you may need to start over with boots that simply fit you better. However, don't do that until you've tried every combination of socks you can find! What works tolerably well for me is greasing up my feet with a whole lot of BodyGlide, which you will find at any running supply store. SmartWool knock-offs and/or Darn Tough socks are all I use, and I recommend them frequently. But, for me, they are useless without first using the BodyGlide. You could also try A&D or just Vaseline too to decrease friction. I feel like BodyGlide may last a little longer but that maybe my imagination. Also, of note, many (most?) of my ultrarunner friends are using thin Injinji socks these days. Not sure they'd be enough protection with boots like yours, but maybe they would make a good first layer.
Lycra socks are an interesting idea and worth a shot, but it would not be my first recommendation because 1) Lycra is thick and might mess with the boots' fit and 2) Lycra holds a lot of heat and blister formation accelerates with increased skin temperature. Maybe you could post and let us know how they work for you?
I really like the idea of padding the tongue. Sounds like some experimentation may be in order. Again, if you try, would love to hear if that works and what material you use.
One other thing to consider, which may not be helpful in this case, but is worth mentioning: Electrolyte/hydration issues are worth taking seriously, especially if you are blister-prone. If your blood cells don't have access to enough salt (whether from sweating a bunch or over-hydrating - even very slightly - and throwing off the ratio), they will off-load water in order to maintain the correct salt concentration. Where does that water end up? In hangs out in the extracellular space and causes trouble. Most of it ends up in the extremities, thanks to gravity. This is why sometimes it's hard to make a fist in the middle of a long sweaty hike.
As for your feet, they would have trouble making a fist too, if that was on their agenda. Instead, their troubles are most apparent in between the layers of their moisture-laden skin. More moisture means more movement between skin layers, increase in edema, and indeed more heat. Add in the mechanical stress of foot against boot against trail, and you are inviting all kinds of fresh blister hell. (FYI There is a great section on blisters in "Training Essentials For Ultrarunning" by Jason Koop, he talks about all this stuff.)
Hopefully you are just a pair of socks away from relief... and hopefully your skin recovers soon enough that you will have time to do some test hikes this week. Peace!